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Micellization and thermodynamics study of ester functionalized picoline-based ionic liquid surfactants in water.

ABSTRACT: A novel series of picoline-based ionic liquid surfactants, N-alkyoxycarbonyl-3-picoline bromides [C _n Empy][Br] (n = 10, 12, 14), have been synthesized. The thermal stability, aggregation behavior and surface activity of the synthetic ionic liquid surfactants were investigated systematically though a series of methods, such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), tensiometry and conductivity. The thermodynamics of micellization of the ionic liquid surfactants solution were studied by using the conductivity method in the temperature range 278.15-318.15 K. The surface activity parameters and thermodynamics parameters were derived, respectively. The enthalpy-entropy compensation effect was further discussed by using relative thermodynamics parameters. It was found that the [C _n Empy][Br] have moderate surface activity, and their critical micelle concentration (CMC) decreased with the ester-functionalized chain length and exhibited a U-shape with temperature. The calculation results of the thermodynamic parameters showed that the micellization processes of [C _n Empy][Br] were spontaneous, endothermic at low temperature and exothermic at higher temperature.

SUBMITTER: Fu D

PROVIDER: S-EPMC9097595 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature

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Micellization and thermodynamics study of ester functionalized picoline-based ionic liquid surfactants in water.

Fu Dong D Gao Xiaoru X Wang Jue J Jiang Haijian H Zheng Mingming M Li Peng P Huang Bo B Kan Kan K Zhang Xiaochen X

RSC advances 20220512 23

A novel series of picoline-based ionic liquid surfactants, N-alkyoxycarbonyl-3-picoline bromides [C n Empy][Br] (n = 10, 12, 14), have been synthesized. The thermal stability, aggregation behavior and surface activity of the synthetic ionic liquid surfactants were investigated systematically though a series of methods, such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), tensiometry and conductivity. The thermodynamics of micellizatio ...[more]

PMID: 35702243

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Project description:The aggregation behavior of two cationic surfactants, i.e., cetyldimethylethanolammonium bromide (CDMEAB) and cetyltributylphosphonium bromide (CTBPB), within an aqueous deep eutectic solvent (DES) is studied. The synthesized DES is composed of 1:2 mole ratio of choline chloride and glycerol and is further characterized by Fourier transform infrared (FTIR) and 1H NMR spectroscopy techniques. The critical micellar concentration (CMC), micellar size, and intermolecular interaction in surfactants within Gly-based DES solutions are investigated by various techniques including surface tension, conductivity, fluorescence, dynamic light scattering (DLS), FTIR, 1H NMR, and two-dimensional (2D) nuclear Overhauser effect spectroscopy (NOESY). The various interfacial properties and thermodynamic parameters are determined in the presence of 5 wt % glyceline (Gly)-based DES in an aqueous solution. The CMC, aggregation number (N agg), and Stern-Volmer constant (K sv) have also been determined by a steady-state fluorescence method. DLS is used to obtain information regarding the size of the aggregates formed by the cationic surfactants in DES solutions. FTIR spectroscopy is used to study the surfactant-DES interactions that tune the micellar structure of the surfactants within the Gly-based DES solution. The functional groups involved in the interactions (H-bonding and electrostatic) are the head groups (HO-CH2-CH2-N+ ion for CDMEAB and quaternary phosphonium (P+) ion for CTBPB) of the surfactants with the -OH-containing Gly DES. The hydrophobic moieties are involved in the hydrophobic interactions. The 1H NMR data show that differences in chemical shifts can provide significant information about the interactions taking place within the system. 1H NMR and NOESY techniques are further employed to strengthen our claim on the feasible structural arrangements within the aqueous surfactant-DES self-assembled structures. It is observed that both the cationic surfactants, i.e., CDMEAB and CTBPB, form self-assembled nanostructures in the Gly-based DES solutions. The present results are expected to be useful for colloidal solutions of DES and their mixtures with water.

Dataset Information

Micellization and thermodynamics study of ester functionalized picoline-based ionic liquid surfactants in water.

Publications

Micellization and thermodynamics study of ester functionalized picoline-based ionic liquid surfactants in water.

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