Electrolyte Reactivity at the Charged Ni-Rich Cathode Interface and Degradation in Li-Ion Batteries.

ABSTRACT: The chemical and electrochemical reactions at the positive electrode-electrolyte interface in Li-ion batteries are hugely influential on cycle life and safety. Ni-rich layered transition metal oxides exhibit higher interfacial reactivity than their lower Ni-content analogues, reacting via mechanisms that are poorly understood. Here, we study the pivotal role of the electrolyte solvent, specifically cyclic ethylene carbonate (EC) and linear ethyl methyl carbonate (EMC), in determining the interfacial reactivity at charged LiNi_0.33Mn_0.33Co_0.33O₂ (NMC111) and LiNi_0.8Mn_0.1Co_0.1O₂ (NMC811) cathodes by using both single-solvent model electrolytes and the mixed solvents used in commercial cells. While NMC111 e

SUBMITTER: Dose WM 

PROVIDER: S-EPMC9098117 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature