Sorption of Strontium to Uraninite and Uranium(IV)-Silicate Nanoparticles.

ABSTRACT: Spent nuclear fuel contains both uranium (U) and high yield fission products, including strontium-90 (⁹⁰Sr), a key radioactive contaminant at nuclear facilities. Both U and ⁹⁰Sr will be present where spent nuclear fuel has been processed, including in storage ponds and tanks. However, the interactions between Sr and U phases under ambient conditions are not well understood. Over a pH range of 4-14, we investigate Sr sorption behavior in contact with two nuclear fuel cycle relevant U(IV) phases: nano-uraninite (UO₂) and U(IV)-silicate nanoparticles. Nano-UO₂ is a product of the anaerobic corrosion of metallic uranium fuel, and UO₂ is also the predominant form of U in ceramic fuels. U(IV)-silicates form stable colloids under the neutral

SUBMITTER: Neill TS 

PROVIDER: S-EPMC9098169 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature