Heterometallic Metal-Organic Framework Based on [Cu₄I₄] and [Hf₆O₈] Clusters for Adsorption of Iodine.

ABSTRACT: Heterometallic metal-organic framework (MOF) as a kind of porous material is very important because of its excellent properties in catalysis, magnetic, sensor, and adsorption fields, but the reasonable design and syntheses of these are still challenging. Herein, we prepared one heterometallic MOF with the formula [Hf₆(μ ₃-OH)₈(OH)₈][(Cu₄I₄) (ina)₄]₂·22DMF (NS-1, ina = isonicotinate). Single-crystal X-ray diffraction analysis revealed that NS-1 is a three-dimensional network with flu topology, constructed from 8-connected [Hf₆(μ ₃-OH)₈(OH)₈]⁸⁺ and 4-connected [Cu₄I₄] clusters as second building

SUBMITTER: Hu H 

PROVIDER: S-EPMC9098963 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature