Unveiling the Synergistic Effect of Ferroelectric Polarization and Domain Configuration for Reversible Zinc Metal Anodes.

ABSTRACT: The tendency of zinc (Zn) anodes to form uncontrolled Zn electrodeposits and the occurrence of side-reactions at Zn-electrolyte interfaces are a fundamental barrier hampering broad applications of aqueous rechargeable Zn-based batteries. Herein, a ferroelectric domain-mediated strategy is proposed to manipulate the Zn plating behavior and achieve controllable Zn growth orientation by coating Zn foil with a ferroelectric tetragonal KTN (t-KTN) layer. The ferroelectric domain of t-KTN single crystals exhibits periodic distribution of upward and downward polarizations, corresponding to alternating positively and negatively charged surfaces. The charged ferroelectric surfaces can manipulate the transfer kinetics of Zn ions and the concentration distribution of anions via the interplay between

SUBMITTER: Chen T 

PROVIDER: S-EPMC9108597 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature