Evidence of carbon-supported porphyrins pyrolyzed for the oxygen reduction reaction keeping integrity.

ABSTRACT: Fe(III) 5,10,15,20-(tetraphenyl)porphyrin chloride (FeTPP) and Co(III) 5,10,15,20-(tetraphenyl)porphyrin chloride (CoTPP) were adsorbed on carbon Vulcan and studied as electrocatalysts for the oxygen reduction reaction (ORR) before and after pyrolysis. The pyrolysis process was also simulated through ab initio molecular dynamic simulations and the minimum energy path for the O₂ dissociation after the interaction with the metal center of the FeTPP and CoTPP were calculated. After the pyrolysis the FeTPP showed the best performances reducing O₂ completely to H₂O with increased limiting current and lower overpotential. Tafel slops for the various catalysts did not change after the pyrolytic process suggesting that the mechanism for the ORR is not affected by t

SUBMITTER: Orellana W 

PROVIDER: S-EPMC9110719 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature