Performance of high temperature phase-stable high entropy oxide (MgCuMnCoFe)O _x in catalytic wet air oxidation of chloroquine phosphate.

ABSTRACT: With the continuous spread of COVID-19, the water pollution problems caused by the abuse of chloroquine phosphate (CQP) as an antiviral drug have attracted wide attention. The cubic Fm-3m spinel high entropy oxide (HEO)-(MgCuMnCoFe)O _x was prepared by coprecipitation method as the catalytic wet air oxidation (CWAO) catalyst to treat CQP simulated wastewater. Through electron spin resonance (ESR) analysis, HEO will stimulate the production of superoxide radical (·O₂ ^-) and hydroxyl radical (·OH) in the wet air oxidation (WAO) process, which accelerates the degradation and mineralization of CQP. Through response surface method (RSM) optimization, the optimal degradation conditions of CQP in CWAO were proposed: initial oxygen pressure of 15 bar,

SUBMITTER: Liu Y 

PROVIDER: S-EPMC9116700 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature