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An UV-photo and ionic dual responsive interpenetrating network hydrogel with shape memory and self-healing properties.

ABSTRACT: Shape memory hydrogels have attracted extensive attention in fields such as artificial tissues, biomimetic devices and diagnostics, and intelligent biosensors. However, the practical applications were hindered by the absence of self-healing capability and multi-stimuli-responsiveness. To address these issues, we developed a shape memory hydrogel with self-healing and dual stimuli-response performance. The hydrogel system was constructed via an interpenetrating network consisting of in situ radical polymerization and host-guest interaction. The hydrogel exhibited rapid self-healing property, which can be stretched after self-healing for 1 min at 25 °C. Besides, the hydrogel displayed varied swelling performance in different light or solvent conditions. Moreover, the hydrogel showed a dual stimuli-responsive shape memory effect to ultraviolet (UV) light and ionic strength in 1 min. Such a shape memory hydrogel with self-healing ability and multi-stimuli-responsive properties will offer an option toward intelligent soft materials for biomedical and bionic research.

SUBMITTER: Li Z

PROVIDER: S-EPMC9116958 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature

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An UV-photo and ionic dual responsive interpenetrating network hydrogel with shape memory and self-healing properties.

Li Ziyi Z Cai Jiwei J Wei Miaohan M Chen Juncheng J

RSC advances 20220518 24

Shape memory hydrogels have attracted extensive attention in fields such as artificial tissues, biomimetic devices and diagnostics, and intelligent biosensors. However, the practical applications were hindered by the absence of self-healing capability and multi-stimuli-responsiveness. To address these issues, we developed a shape memory hydrogel with self-healing and dual stimuli-response performance. The hydrogel system was constructed <i>via</i> an interpenetrating network consisting of <i>in ...[more]

PMID: 35693233

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Project description:Stimuli-responsive actuating hydrogels response to the external stimulus with complex deformation behaviors based on the programmable anisotropic structure design are one of the most important smart soft materials, which have great potential applications in artificial muscles, smart values, and mini-robots. However, the anisotropic structure of one actuating hydrogel can only be programmed one time, which can only provide single actuating performance, and subsequently, has severely limited their further applications. Herein, we have explored a novel SMP/hydrogel hybrid actuator through combining polyurethane shape memory polymer (PU SMP) layer and pH-responsive polyacrylic-acid (PAA) hydrogel layer by a napkin with UV-adhesive. Owing to both the super-hydrophilicity and super-lipophilicity of the cellulose-fiber based napkin, the SMP and the hydrogel can be bonded firmly by the UV-adhesive in the napkin. More importantly, this bilayer hybrid 2D sheet can be programmed by designing a different temporary shape in heat water which can be fixed easily in cool water to achieve various fixed shapes. This hybrid with a fixed temporary shape can achieve complex actuating performance based on the bi-functional synergy of temperature-triggered SMP and pH-responsive hydrogel. The relatively high modulus PU SMP achieved high to 87.19% and 88.92% shape-fixing ratio, respectively, correspond to bending and folding shapes. The hybrid actuator can actuate with the 25.71 °/min actuating speed. Most importantly, one SMP/hydrogel bi-layer hybrid sheet was repeatedly programmed at least nine times in our research to fix various temporary 1D, 2D and 3D shapes, including bending, folding and spiraling shapes. As a result, only one SMP/hydrogel hybrid can provide various complex stimuli-responsive actuations, including the reversable bending-straightening, spiraling-unspiraling. A few of the intelligent devices have been designed to simulate the movement of the natural organisms, such as bio-mimetic "paw", "pangolin" and "octopus". This work has developed a new SMP/hydrogel hybrid with excellent multi-repeatable (≥9 times) programmability for high-level complex actuations, including the 1D to 2D bending and the 2D to 3D spiraling actuations, which also provides a new strategy to design other new soft intelligent materials and systems.

Dataset Information

An UV-photo and ionic dual responsive interpenetrating network hydrogel with shape memory and self-healing properties.

Publications

An UV-photo and ionic dual responsive interpenetrating network hydrogel with shape memory and self-healing properties.

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