Integrating charge mobility, stability and stretchability within conjugated polymer films for stretchable multifunctional sensors.

ABSTRACT: Conjugated polymers (CPs) are promising semiconductors for intrinsically stretchable electronic devices. Ideally, such CPs should exhibit high charge mobility, excellent stability, and high stretchability. However, converging all these desirable properties in CPs has not been achieved via molecular design and/or device engineering. This work details the design, synthesis and characterization of a random polythiophene (RP-T50) containing ~50 mol% of thiophene units with a thermocleavable tertiary ester side chain and ~50 mol% of unsubstituted thiophene units, which, upon thermocleavage of alkyl chains, shows significant improvement of charge mobility and stability. Thermal annealing a RP-T50 film coated on a stretchable polydimethylsiloxane substrate spontaneously generates wrinkling in the

SUBMITTER: Son SY 

PROVIDER: S-EPMC9117230 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature