MOF-Derived Long Spindle-like Carbon-Coated Ternary Transition-Metal-Oxide Composite for Lithium Storage.

ABSTRACT: Fe₃O₄ is a promising alternative for next-generation lithium-ion batteries (LIBs). However, its poor cycle stability due to the large volume effect during cycling and poor conductivity hinders its application. Herein, we have successfully designed and prepared a carbon-coated ternary transition-metal-oxide composite (noted as (FeCoNi)₃O₄@C), which is derived from FeCoNi-MOF-74 (denoted as FeCoNi-211-24). (FeCoNi)₃O₄@C perfectly inherited the long spindle-shaped precursor structure, and (FeCoNi)₃O₄ particles grew in situ on the precursor surface. The ordered particles and the carbon-coated structure inhibited the agglomeration of particles, improving the material's cycle stability and conductivity

SUBMITTER: Wu L 

PROVIDER: S-EPMC9118374 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature