Dataset Information

Capillary Bridges on Hydrophobic Surfaces: Analytical Contact Angle Determination.

ABSTRACT: The capillary bridge probe method was introduced previously as a high-accuracy contact angle determination method relying on capillary bridges on hydrophilic and superhydrophilic surfaces [Nagy, N. Langmuir 2019, 35 (15), 5202-5212]. In this work, the behavior of r-ϑ type liquid bridges was studied and the contact angles were determined on hydrophobic surfaces. The equilibrium shape of these liquid bridges often does not contain the neck or haunch region. The unknown neck/haunch radius prevents analytical evaluation of the capillary bridge shape. In this work, the possible incomplete liquid bridge shapes were classified and a novel procedure was developed for the Delaunay's analytical solution-based evaluation of these states. The parameter space of the capillary bridges was visualized and described without using dimensionless variables. As a demonstration, Cyclo Olefin Polymer and PTFE surfaces were investigated, with advancing and receding contact angles determined and compared to the results of sessile drop measurements.

SUBMITTER: Nagy N

PROVIDER: S-EPMC9118539 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Capillary Bridges on Hydrophobic Surfaces: Analytical Contact Angle Determination.

Nagy Norbert N

Langmuir : the ACS journal of surfaces and colloids 20220506 19

The capillary bridge probe method was introduced previously as a high-accuracy contact angle determination method relying on capillary bridges on hydrophilic and superhydrophilic surfaces [Nagy, N. Langmuir 2019, 35 (15), 5202-5212]. In this work, the behavior of r-ϑ type liquid bridges was studied and the contact angles were determined on hydrophobic surfaces. The equilibrium shape of these liquid bridges often does not contain the neck or haunch region. The unknown neck/ha ...[more]

PMID: 35523001

Similar Datasets

Project description:Polydimethylsiloxane (PDMS), a silicone elastomer, is increasingly being used in health and biomedical fields due to its excellent optical and mechanical properties. Its biocompatibility and resistance to biodegradation led to various applications (e.g., lung on a chip replicating blood flow, medical interventions, and diagnostics). The many advantages of PDMS are, however, partially offset by its inherent hydrophobicity, which makes it unsuitable for applications needing wetting, thus requiring the hydrophilization of its surface by exposure to UV or O2 plasma. Yet, the elastomeric state of PDMS translates in a slow, hours to days, process of reducing its surface hydrophilicity-a process denominated as hydrophobic recovery. Using Fourier transform infrared spectroscopy (FTIR) and atomic force microscopy (AFM), the present study details the dynamics of hydrophobic recovery of PDMS, on flat bare surfaces and on surfaces embedded with hydrophilic beads. It was found that a thin, stiff, hydrophilic, silica film formed on top of the PDMS material, following its hydrophilization by UV radiation. The hydrophobic recovery of bare PDMS material is the result of an overlap of various nano-mechanical, and diffusional processes, each with its own dynamics rate, which were analyzed in parallel. The hydrophobic recovery presents a hysteresis, with surface hydrophobicity recovering only partially due to a thin, but resilient top silica layer. The monitoring of hydrophobic recovery of PDMS embedded with hydrophilic beads revealed that this is delayed, and then totally stalled in the few-micrometer vicinity of the embedded hydrophilic beads. This region where the hydrophobic recovery stalls can be used as a good approximation of the depth of the resilient, moderately hydrophilic top layer on the PDMS material. The complex processes of hydrophilization and subsequent hydrophobic recovery impact the design, fabrication, and operation of PDMS materials and devices used for diagnostics and medical procedures. Consequently, especially considering the emergence of new surgical procedures using elastomers, the impact of hydrophobic recovery on the surface of PDMS warrants more comprehensive studies.

Dataset Information

Capillary Bridges on Hydrophobic Surfaces: Analytical Contact Angle Determination.

Publications

Capillary Bridges on Hydrophobic Surfaces: Analytical Contact Angle Determination.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets