Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century.

ABSTRACT: CH₄ is the most abundant reactive greenhouse gas and a complete understanding of its atmospheric fate is needed to formulate mitigation policies. Current chemistry-climate models tend to underestimate the lifetime of CH₄, suggesting uncertainties in its sources and sinks. Reactive halogens substantially perturb the budget of tropospheric OH, the main CH₄ loss. However, such an effect of atmospheric halogens is not considered in existing climate projections of CH₄ burden and radiative forcing. Here, we demonstrate that reactive halogen chemistry increases the global CH₄ lifetime by 6-9% during the 21st century. This effect arises from significant halogen-mediated decrease, mainly by iodine and bromine, in OH-driven CH₄ loss t

SUBMITTER: Li Q 

PROVIDER: S-EPMC9120080 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature