Imine-Linked Covalent Organic Framework with a Naphthalene Moiety as a Sensitive Phosphate Ion Sensing.

ABSTRACT: Due to the excellent ion-sensing potential of covalent organic frameworks (COFs), the new imine-linked conjugated COF (IC-COF) is synthesized through a water-based synthesis reaction between 1,5-diaminonaphthalene and 2,4,6-tris(4-formylphenoxy)-1,3,5-triazine to create a luminescence sensor. It is noteworthy that the green synthesized IC-COF shows excellent selectivity to phosphate ions (PO₄^3-) with a detection limit of 0.61 μM. The recyclability performance of IC-COF is high, indicating that it can be reused without a significant reduction in performance (5.2% decline after 5 cycles). Theoretical calculations using the density functional theory are performed on the IC-COF-PO₄^3- and IC-COF-Cu⁺ complexes to explore the sensing mechanis

SUBMITTER: Afshari M 

PROVIDER: S-EPMC9121346 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature