Chiral Lanthanum Metal-Organic Framework with Gated CO₂ Sorption and Concerted Framework Flexibility.

ABSTRACT: A metal-organic framework (MOF) CTH-17 based on lanthanum(III) and the conformationally chiral linker 1,2,3,4,5,6-hexakis(4-carboxyphenyl)benzene, cpb^6-: [La₂(cpb)]·1.5dmf was prepared by the solvothermal method in dimethylformamide (dmf) and characterized by variable-temperature X-ray powder diffraction (VTPXRD), variable-temperature X-ray single-crystal diffraction (SCXRD), and thermogravimetric analysis (TGA). CTH-17 is a rod-MOF with new topology och. It has high-temperature stability with Sohncke space groups P6₁22/P6₅22 at 90 K and P622 at 300 and 500 K, all phases characterized with SCXRD and at 293 K also with three-dimensional (3D) electron diffraction. VTPXRD indicates a third phase appearing af

SUBMITTER: Amombo Noa FM 

PROVIDER: S-EPMC9122260 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature