Efficiency enhancement of ruthenium-based DSSCs employing A-π-D-π-A organic Co-sensitizers.

ABSTRACT: A new bipyridyl Ru(ii) sensitizer incorporating triphenylamine and the 3,4-ethylenedioxythiophene (EDOT) ancillary ligand IMA5 was synthesized for dye-sensitized solar cells (DSSCs). The performance of these DSSCs has been enhanced via di-anchoring metal-free organic sensitizers, denoted IMA1-4, with structural motif A-π-D-π-A and incorporating phenyl-dibenzothiophene-phenyl (Ph-DBT-Ph) as the main building block but with different anchoring groups (A). These new organic sensitizers were well-characterized and used as efficient co-sensitizers. Their photophysical, electrochemical and photovoltaic properties were studied. Furthermore, molecular modeling studies using DFT calculations were used to investigate their suitability as effective sensitizers/co-sensitizers. The molecular orb

SUBMITTER: Abdellah IM 

PROVIDER: S-EPMC9127656 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature