Electrochemical oxygen reduction to hydrogen peroxide at practical rates in strong acidic media.

ABSTRACT: Electrochemical oxygen reduction to hydrogen peroxide (H₂O₂) in acidic media, especially in proton exchange membrane (PEM) electrode assembly reactors, suffers from low selectivity and the lack of low-cost catalysts. Here we present a cation-regulated interfacial engineering approach to promote the H₂O₂ selectivity (over 80%) under industrial-relevant generation rates (over 400 mA cm^-2) in strong acidic media using just carbon black catalyst and a small number of alkali metal cations, representing a 25-fold improvement compared to that without cation additives. Our density functional theory simulation suggests a "shielding effect" of alkali metal cations which squeeze away the catalyst/electrolyte interfacial protons and thus prevent f

SUBMITTER: Zhang X 

PROVIDER: S-EPMC9130276 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature