Metalloenzyme-Inspired Ce-MOF Catalyst for Oxidative Halogenation Reactions.

ABSTRACT: The structure of UiO-66(Ce) is formed by CeO_2-x defective nanoclusters connected by terephthalate ligands. The initial presence of accessible Ce³⁺ sites in the as-synthesized UiO-66(Ce) has been determined by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR)-CO analyses. Moreover, linear scan voltammetric measurements reveal a reversible Ce⁴⁺/Ce³⁺ interconversion within the UiO-66(Ce) material, while nanocrystalline ceria shows an irreversible voltammetric response. This suggests that terephthalic acid ligands facilitate charge transfer between subnanometric metallic nodes, explaining the higher oxidase-like activity of UiO-66(Ce) compared to nanoceria for the mild oxidation of organic dyes under aerobic conditio

SUBMITTER: Rojas-Buzo S 

PROVIDER: S-EPMC9131423 | biostudies-literature | 2021 Jul

REPOSITORIES: biostudies-literature