Antisymmetric Spin Exchange in a μ-1,2-Peroxodicopper(II) Complex with an Orthogonal Cu-O-O-Cu Arrangement and S = 1 Spin Ground State Characterized by THz-EPR.

ABSTRACT: A unique type of Cu₂/O₂ adduct with orthogonal (close to 90°) Cu-O-O-Cu arrangement has been proposed for initial stages of O₂ binding at biological type III dicopper sites, and targeted ligand design has now allowed us to emulate such an adduct in a pyrazolate-based μ-η¹ :η¹-peroxodicopper(II) complex (2) with Cu-O-O-Cu torsion φ of 87°, coined ^⊥ P intermediate. Full characterization of 2, including X-ray diffraction (d _O-O = 1.452 Å) and Raman spectroscopy (ν̃_O-O = 807 cm^-1), completes a series of closely related Cu₂/O₂ intermediates featuring μ-η¹ :η¹-peroxodicopper(II) cores with φ r

SUBMITTER: Lohmiller T 

PROVIDER: S-EPMC9131480 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature