Dual electrochemical and chemical control in atom transfer radical polymerization with copper electrodes.

ABSTRACT: In Atom Transfer Radical Polymerization (ATRP), Cu⁰ acts as a supplemental activator and reducing agent (SARA ATRP) by activating alkyl halides and (re)generating the Cu^I activator through a comproportionation reaction, respectively. Cu⁰ is also an unexplored, exciting metal that can act as a cathode in electrochemically mediated ATRP (eATRP). Contrary to conventional inert electrodes, a Cu cathode can trigger a dual catalyst regeneration, simultaneously driven by electrochemistry and comproportionation, if a free ligand is present in solution. The dual regeneration explored herein allowed for introducing the concept of pulsed galvanostatic electrolysis (PGE) in eATRP. During a PGE, the process alternates between a period of constant current e

SUBMITTER: De Bon F 

PROVIDER: S-EPMC9132085 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature