Tuning the Photophysical Properties of Homoleptic Tris-Cyclometalated Ir(III) Complexes by Facile Modification of the Imidazo-Phenanthridine and Their Application to Phosphorescent Organic Light-Emitting Diodes.

ABSTRACT: To explore the excited-state electronic structure of the blue-emitting Ir(dmp)₃ dopant material (dmp = 3-(2,6-dimethylphenyl)-7-methylimidazo[1,2-f]phenanthridine), which is notable for durable blue phosphorescent organic light-emitting diode (PhOLED), a series of homoleptic dmp-based Ir(III) complexes (DMP-R, tris[3-(2,6-dimethylphenyl)-7-R-imidazo[1,2-f]phenanthridin-12-yl-κC ¹²,κN ¹]iridium, R = H, CH₃, F, and CF₃) were prepared by introducing an electron-donating group (EDG; -CH₃) or an electron-withdrawing group (EWG; -F and -CF₃) at the 7-position of the imidazo-phenanthridine ligand. The photophysical analysis demonstrated that the alteration from EDG to EWGs

SUBMITTER: Kim SY 

PROVIDER: S-EPMC9134233 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature