Structural Diversity in Multicomponent Nanocrystal Superlattices Comprising Lead Halide Perovskite Nanocubes.

ABSTRACT: Nanocrystal (NC) self-assembly is a versatile platform for materials engineering at the mesoscale. The NC shape anisotropy leads to structures not observed with spherical NCs. This work presents a broad structural diversity in multicomponent, long-range ordered superlattices (SLs) comprising highly luminescent cubic CsPbBr₃ NCs (and FAPbBr₃ NCs) coassembled with the spherical, truncated cuboid, and disk-shaped NC building blocks. CsPbBr₃ nanocubes combined with Fe₃O₄ or NaGdF₄ spheres and truncated cuboid PbS NCs form binary SLs of six structure types with high packing density; namely, AB₂, quasi-ternary ABO₃, and ABO₆ types as well as previously known NaCl, AlB₂, and CuAu types. I

SUBMITTER: Cherniukh I 

PROVIDER: S-EPMC9134504 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature