Solution-processable microporous polymer platform for heterogenization of diverse photoredox catalysts.

ABSTRACT: In contemporary organic synthesis, substances that access strongly oxidizing and/or reducing states upon irradiation have been exploited to facilitate powerful and unprecedented transformations. However, the implementation of light-driven reactions in large-scale processes remains uncommon, limited by the lack of general technologies for the immobilization, separation, and reuse of these diverse catalysts. Here, we report a new class of photoactive organic polymers that combine the flexibility of small-molecule dyes with the operational advantages and recyclability of solid-phase catalysts. The solubility of these polymers in select non-polar organic solvents supports their facile processing into a wide range of heterogeneous modalities. The active sites, embedded within porous microstruct

SUBMITTER: Liu RY 

PROVIDER: S-EPMC9142596 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature