A New Compartmentalized Scale (P_N) for Measuring Polarity Applied to Novel Ether-Functionalized Amino Acid Ionic Liquids.

ABSTRACT: Functionalized and environmentally friendly ionic liquids are required in many fields, but convenient methods for measuring their polarity are lacking. Two novel ether-functionalized amino acid ionic liquids, 1-(2-methoxyethyl)-3-methylimidazolium alanine ([C₁OC₂mim][Ala]) and 1-(2-ethoxyethyl)-3-methylimidazolium alanine ([C₂OC₂mim][Ala]), were synthesized by a neutralization method and their structures confirmed by NMR spectroscopy. Density, surface tension, and refractive index were determined using the standard addition method. The strength of intermolecular interactions within these ionic liquids was examined in terms of standard entropy, lattice energy, and association enthalpy. A new polarity scale, P_N, is now proposed, w

SUBMITTER: Zheng X 

PROVIDER: S-EPMC9144623 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature