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Four New Sesquiterpenoids from the Rice Fermentation of Antrodiella albocinnamomea.


ABSTRACT: Albocimea B-E (1-4), four new sesquiterpenoids, and four known compounds, steperoxide A (5), dankasterone (6), 1H-indole-3-carboxylic acid (7), and (+)-formylanserinone B (8), were isolated from the rice fermentation of the fungus Antrodiella albocinnamomea. The structures of new compounds were elucidated by comprehensive spectroscopic techniques, the planar structures of new compounds were determined by comprehensive spectroscopic techniques, and their absolute configurations were confirmed via gauge-independent atomic orbital calculations (GIAO), calculation of the electronic circular dichroism (ECD), and optical rotation (OR). These were determined by spectroscopic data analysis.

SUBMITTER: Guo M 

PROVIDER: S-EPMC9147044 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature

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Four New Sesquiterpenoids from the Rice Fermentation of <i>Antrodiella albocinnamomea</i>.

Guo Min M   Liang Ying-Zhong YZ   Cui Xiu-Ming XM   Shao Lin-Jiao LJ   Li Yin-Fei YF   Yang Xiao-Yan XY  

Molecules (Basel, Switzerland) 20220523 10


Albocimea B-E (<b>1</b>-<b>4</b>), four new sesquiterpenoids, and four known compounds, steperoxide A (<b>5</b>), dankasterone (<b>6</b>), 1<i>H</i>-indole-3-carboxylic acid (<b>7</b>), and (+)-formylanserinone B (<b>8</b>), were isolated from the rice fermentation of the fungus <i>Antrodiella albocinnamomea</i>. The structures of new compounds were elucidated by comprehensive spectroscopic techniques, the planar structures of new compounds were determined by comprehensive spectroscopic techniqu  ...[more]

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