Analyzing the Local Electronic Structure of Co₃O₄ Using 2p3d Resonant Inelastic X-ray Scattering.

ABSTRACT: We present the cobalt 2p3d resonant inelastic X-ray scattering (RIXS) spectra of Co₃O₄. Guided by multiplet simulation, the excited states at 0.5 and 1.3 eV can be identified as the ⁴ T ₂ excited state of the tetrahedral Co²⁺ and the ³ T _2g excited state of the octahedral Co³⁺, respectively. The ground states of Co²⁺ and Co³⁺ sites are determined to be high-spin ⁴ A ₂(T _d ) and low-spin ¹ A _1g (O_h ), respectively. It indicates that the high-spin Co²⁺ is the magnetically active site in Co₃O₄. Additionally, the ligand-to-met

SUBMITTER: Wang RP 

PROVIDER: S-EPMC9150098 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature