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Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo₂LiH₂, Mo₂Li₂H₄, and Mo₆Li₉H₁₈ Clusters.

ABSTRACT: The reactions of LiAlH₄ as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the coordination of bulky Ad^Dipp2 ligands result in the respective coordination of one and two molecules of (thf)LiH, with the generation of complexes exhibiting one and two HLi(thf)H ligands extending across the Mo≣Mo bond (Ad^Dipp2 = HC(NDipp)₂; Dipp = 2,6-ⁱPr₂C₆H₃; thf = tetrahydrofuran, C₄H₈O). A theoretical study reveals the formation of Mo-H-Li three-center-two-electron bonds, supplemented by the coordination of the Mo≣Mo bond to the Li ion. Attempts to construct a [Mo₂{HLi(thf)H}₃(Ad^Dipp2)] molecular architecture led to

SUBMITTER: Perez-Jimenez M

PROVIDER: S-EPMC9157502 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Dataset Information

Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo₂LiH₂, Mo₂Li₂H₄, and Mo₆Li₉H₁₈ Clusters.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo₂LiH₂, Mo₂Li₂H₄, and Mo₆Li₉H₁₈ Clusters.