Composition-driven archetype dynamics in polyoxovanadates.

ABSTRACT: Molecular metal oxides often adopt common structural frameworks (i.e. archetypes), many of them boasting impressive structural robustness and stability. However, the ability to adapt and to undergo transformations between different structural archetypes is a desirable material design feature offering applicability in different environments. Using systems thinking approach that integrates synthetic, analytical and computational techniques, we explore the transformations governing the chemistry of polyoxovanadates (POVs) constructed of arsenate and vanadate building units. The water-soluble salt of the low nuclearity polyanion [V₆As₈O₂₆]^4- can be effectively used for the synthesis of the larger spherical (i.e. kegginoidal) mixed-valen

SUBMITTER: Kondinski A 

PROVIDER: S-EPMC9159092 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature