Operando pH Measurements Decipher H⁺/Zn²⁺ Intercalation Chemistry in High-Performance Aqueous Zn/δ-V₂O₅ Batteries.

ABSTRACT: Vanadium oxides have been recognized to be among the most promising positive electrode materials for aqueous zinc metal batteries (AZMBs). However, their underlying intercalation mechanisms are still vigorously debated. To shed light on the intercalation mechanisms, high-performance δ-V₂O₅ is investigated as a model compound. Its structural and electrochemical behaviors in the designed cells with three different electrolytes, i.e., 3 m Zn(CF₃SO₃)₂/water, 0.01 M H₂SO₄/water, and 1 M Zn(CF₃SO₃)₂/acetonitrile, demonstrate that the conventional structural and elemental characterization methods cannot adequately clarify the separate roles of H⁺ and Zn²⁺ intercalati

SUBMITTER: Liu X 

PROVIDER: S-EPMC9161344 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature