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Oxidative degradation of sulfamethoxazole from secondary treated effluent by ferrate(VI): kinetics, by-products, degradation pathway and toxicity assessment.


ABSTRACT: Sulfamethoxazole (SMX) is a typical antibiotic in the world, which is frequently detected in the aquatic environment. The current study was aimed to investigate the SMX degradation in secondary treated wastewater using potassium Ferrate [Fe(VI)]. The effects of various experimental conditions, EDTA and phosphate as chelating agents, and toxicity assessment were also considered. Secondary treated effluent was spiked with predefined SMX concentrations, and after desired reaction time with Fe(VI), residual SMX was measured using HPLC. Results indicated that SMX degradation by Fe(VI) was favored under acidic condition, where 90% of SMX degradation was achieved after 120 min. Fe(VI) and SMX reaction obeyed first-order kinetic; meantime, the SMX degradation rate under pH 3 was 7.6 times higher t

SUBMITTER: Jebalbarezi B 

PROVIDER: S-EPMC9163226 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature