Magnetic phase diagram of the solid solution LaMn₂(Ge_1-xSi_x)₂ (0 ≤ x ≤ 1) unraveled by powder neutron diffraction.

ABSTRACT: The structural and magnetic properties of the ThCr₂Si₂-type solid solution LaMn₂(Ge_1-xSi_x)₂ (x = 0.0 to 1.0) have been investigated employing a combination of X-ray diffraction, magnetization and neutron diffraction measurements, which allowed establishing a magnetic composition-temperature phase diagram. Substitution of Ge by Si leads to a compression of the unit cell, which affects the magnetic exchange interactions. In particular, the magnetic structure of LaMn₂(Ge_1-xSi_x)₂ is strongly affected by the unit cell parameter c, which is related to the distance between adjacent Mn layers. Commensurate antiferromagnetic layers and a canted ferromagnetic structure dominate the Si-rich p

SUBMITTER: Siebeneichler S 

PROVIDER: S-EPMC9166718 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature