Intercalation-driven ferroelectric-to-ferroelastic conversion in a layered hybrid perovskite crystal.

ABSTRACT: Two-dimensional (2D) organic-inorganic hybrid perovskites have attracted intense interests due to their quantum well structure and tunable excitonic properties. As an alternative to the well-studied divalent metal hybrid perovskite based on Pb²⁺, Sn²⁺ and Cu²⁺, the trivalent metal-based (eg. Sb³⁺ with ns2 outer-shell electronic configuration) hybrid perovskite with the A₃M₂X₉ formula (A = monovalent cations, M = trivalent metal, X = halide) offer intriguing possibilities for engineering ferroic properties. Here, we synthesized 2D ferroelectric hybrid perovskite (TMA)₃Sb₂Cl₉ with measurable in-plane and out-of-plane polarization. Interestingly, (TMA)₃Sb₂Cl

SUBMITTER: Wu Z 

PROVIDER: S-EPMC9166815 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature