Crystal and molecular structures of fac-[Re(Bid)(PPh₃)(CO)₃] [Bid is tropolone (TropH) and tribromotropolone (TropBr₃H)].

ABSTRACT: Two rhenium complexes, namely, fac-tricarbonyl(triphenylphosphane-κP)(tropolonato-κ²O,O')rhenium(I), [Re(C₇H₅O₂)(C₁₈H₁₅P)(CO)₃] or fac-[Re(Trop)(PPh₃)(CO)₃] (1), and fac-tricarbonyl(3,5,7-tribromotropolonato-κ²O,O')(triphenylphosphane-κP)rhenium(I), [Re(C₇H₂Br₃O₂)(C₁₈H₁₅P)(CO)₃] or fac-[Re(TropBr₃)(PPh₃)(CO)₃] (2) (TropH is tropolone and and TropBr₃H is tribromotropolone), were synthesized and their crystal and molecular structures confirmed by single-crystal X-ray diffraction. Both crystallized in the space group P-1 and display an array of inter- and intramolec

SUBMITTER: Schutte-Smith M 

PROVIDER: S-EPMC9167630 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature