Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications.

ABSTRACT: We present an update and revision to our 2010 review on the topic of proton-coupled electron transfer (PCET) reagent thermochemistry. Over the past decade, the data and thermochemical formalisms presented in that review have been of value to multiple fields. Concurrently, there have been advances in the thermochemical cycles and experimental methods used to measure these values. This Review (i) summarizes those advancements, (ii) corrects systematic errors in our prior review that shifted many of the absolute values in the tabulated data, (iii) provides updated tables of thermochemical values, and (iv) discusses new conclusions and opportunities from the assembled data and associated techniques. We advocate for updated thermochemical cycles that provide greater clarity and reduce experimen

SUBMITTER: Agarwal RG 

PROVIDER: S-EPMC9175307 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature