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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation.


ABSTRACT: A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

SUBMITTER: Ma Y 

PROVIDER: S-EPMC9178507 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature