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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation.

ABSTRACT: A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.

SUBMITTER: Ma Y 

PROVIDER: S-EPMC9178507 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation.

Ma Yangyang Y   Li Jiayun J   Bai Ying Y   Peng Jiajian J  

Current organic synthesis 20210101 5

A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KO<sup>t</sup>Bu as an additive, the reaction time and activation energy are greatly reduced. ...[more]

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