Synthesis, Structure, and Properties of Complexes Based on 2,4-Bis-(triazol-1-yl)benzoic Acid as a Ligand.

ABSTRACT: Using 2,4-bis-(triazol-1-yl)-benzoic acid as the main ligand and terephthalic acid (TPA) as the auxiliary ligand, combined with Cd(NO₃)₂·4H₂O and Zn(NO₃)₂·6H₂O, self-assembly under solvothermal conditions gave three novel complexes: [Cd_0.5(L)(H₂O)] (1), [Cd(L)(TPA)_0.5(H₂O)]·H₂O (2), and [Zn(L)(TPA)_0.5]·H₂O (3) (TPA = terephthalic acid). The crystal structure test showed that complex 1 belongs to the triclinic crystal system and the P1̅ space group and complexes 2 and 3 belong to the monoclinic crystal system and the P2₁/c space group. Solid-state fluorescence experiments show

SUBMITTER: Yang Y 

PROVIDER: S-EPMC9178759 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature