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Deposition of Nanosized Amino Acid Functionalized Bismuth Oxido Clusters on Gold Surfaces.


ABSTRACT: Bismuth compounds are of growing interest with regard to potential applications in catalysis, medicine, and electronics, for which their environmentally benign nature is one of the key factors. One thing that currently hampers the further development of bismuth oxido-based materials, however, is the often low solubility of the precursors, which makes targeted immobilisation on substrates challenging. We present an approach towards the solubilisation of bismuth oxido clusters by introducing an amino carboxylate as a functional group. For this purpose, the bismuth oxido cluster [Bi38O45(NO3)20(dmso)28](NO3)4·4dmso (dmso = dimethyl sulfoxide) was reacted with the sodium salt of tert-butyloxycabonyl (Boc)-prote

SUBMITTER: Morgenstern A 

PROVIDER: S-EPMC9182479 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature