Optimization of Electrolytes for High-Performance Aqueous Aluminum-Ion Batteries.

ABSTRACT: Aqueous rechargeable batteries based on aluminum chemistry have become the focus of immense research interest owing to their earth abundance, low cost, and the higher theoretical volumetric energy density of this element compared to lithium-ion batteries. Efforts to harness this huge potential have been hindered by the narrow potential window of water and by passivating effects of the high-electrical band-gap aluminum oxide film. Herein, we report a high-performing aqueous aluminum-ion battery (AIB), which is constructed using a Zn-supported Al alloy, an aluminum bis(trifluoromethanesulfonyl)imide (Al[TFSI]₃) electrolyte, and a MnO₂ cathode. The use of Al[TFSI]₃ significantly extends the voltage window of the electrolyte and enables the cell to access Al

SUBMITTER: Ejigu A 

PROVIDER: S-EPMC9185688 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature