Co-catalysis of trace dissolved Fe(iii) with biochar in hydrogen peroxide activation for enhanced oxidation of pollutants.

ABSTRACT: Activation of hydrogen peroxide (H₂O₂) with biochar is a sustainable and low-cost approach for advanced oxidation of organic pollutants, but faces the challenge of a low yield of hydroxyl radical (˙OH). Herein, we hypothesize that the activation efficiency of H₂O₂ can be enhanced through co-catalysis of trace dissolved iron (Fe) with biochar. Two biochar samples derived from different feedstock, namely LB from liquor-making residue and WB from wood sawdust, were tested in the co-catalytic systems using trace Fe(iii) (0.3 mg L^-1). The cumulative ˙OH production in [Fe(iii) + LB]/H₂O₂ was measured to be 3.28 times that in LB/H₂O₂, while the cumulative ˙OH production in [Fe(iii) + WB]/H₂

SUBMITTER: Feng D 

PROVIDER: S-EPMC9186116 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature