Conformationally dynamic copper coordination complexes.

ABSTRACT: The interplay between oxidation state and coordination geometry dictates both kinetic and thermodynamic properties underlying electron transfer events in copper coordination complexes. An ability to stabilize both Cu^I and Cu^II oxidation states in a single conformationally dynamic chelating ligand allows access to controlled redox reactivity. We report an analysis of the conformational dynamics of Cu^I complexes bearing dipicolylaniline (dpa^R) ligands, with ortho-aniline substituents R = H and R = OMe. Variable temperature NMR spectroscopy and electrochemical experiments suggest that in solution at room temperature, an equilibrium exists between two conformers. Two metal-centered redox events are observed which, bolstered by structural infor

SUBMITTER: Charette BJ 

PROVIDER: S-EPMC9188647 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature