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High-Density Oxygen Doping of Conductive Metal Sulfides for Better Polysulfide Trapping and Li2 S-S8  Redox Kinetics in High Areal Capacity Lithium-Sulfur Batteries.


ABSTRACT: Exploring new materials and methods to achieve high utilization of sulfur with lean electrolyte is still a common concern in lithium-sulfur batteries. Here, high-density oxygen doping chemistry is introduced for making highly conducting, chemically stable sulfides with a much higher affinity to lithium polysulfides. It is found that doping large amounts of oxygen into NiCo2 S4 is feasible and can make it outperform the pristine oxides and natively oxidized sulfides. Taking the advantages of high conductivity, chemical stability, the introduced large Li-O interactions, and activated Co (Ni) facets for catalyzing Sn 2- , the NiCo2 (O-S)4 is able to accelerate the Li2 S-S8 redox kinetics. Specifically, lit

SUBMITTER: Li Y 

PROVIDER: S-EPMC9189686 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature