Arsolyl-supported intermetallic dative bonding.
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ABSTRACT:
SUBMITTER: Kirk RM
PROVIDER: S-EPMC9200119 | biostudies-literature | 2022 Jun
REPOSITORIES: biostudies-literature
Publications
Arsolyl-supported intermetallic dative bonding.
Kirk Ryan M RM Hill Anthony F AF
Chemical science 20220504 23
The first examples of late transition metal η<sup>5</sup>-arsolyls (L = CO, P(OMe)<sub>3</sub>; R = Ph, Me, Et, SiMe<sub>3</sub>; R' = Ph, H, Me, Et, Me) serve as ditopic donors to extraneous metal centres (M = Pt<sup>II</sup>, Au<sup>I</sup>, Hg<sup>II</sup>) through both conventional As → M and polar-covalent (dative) Co → M interactions. ...[more]
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