A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics.

ABSTRACT: Host-guest interactions play critical roles in achieving switchable structures and functionalities in porous materials, but design and control remain challenging. Here, we report a two-dimensional porous magnetic compound, [Fe^II(prentrz)₂Pd^II(CN)₄] (prentrz = (1E,2E)-3-phenyl-N-(4H-1,2,4-triazol-4-yl)prop-2-en-1-imine), which exhibits an atypical pore transformation that directly entangles with a spin state transition in response to water adsorption. In this material, the adsorption-induced, non-uniform pedal motion of the axial prentrz ligands and the crumpling/unfolding of the layer structure actuate a reversible narrow quasi-discrete pore (nqp) to large channel-type pore (lcp) change that leads to a pore rearrangement associated with simultane

SUBMITTER: Xue JP 

PROVIDER: S-EPMC9206640 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature