Construction and Property Investigation of Serial Pillar[5]arene-Based [1]Rotaxanes.

ABSTRACT: Although the construction and application of pillar[5]arene-based [1]rotaxanes have been extensively studied, the types of stoppers for them are limited. In this work, we designed and prepared three series of pillar[5]arene-based [1]rotaxanes (P5[1]Rs) with pentanedione derivatives, azobenzene derivatives, and salicylaldehyde derivatives as the stoppers, respectively. The obtained P5[1]Rs were fully characterized by NMR (¹H, ¹³C, and 2D), mass spectra, and single-crystal X-ray analysis. We found that the synergic C-H···π, C-H···O interactions and N-H···O, O-H···N hydrogen bonding are the key to the stability of [1]rotaxanes. This work not only enriched the diversity of pillar[n]arene family but also gave a big boost to the pillar[n]arene-based mechanical

SUBMITTER: Ma L 

PROVIDER: S-EPMC9210957 | biostudies-literature | 2022

REPOSITORIES: biostudies-literature