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Unravelling the non-classicality role in Gaussian heat engines.

ABSTRACT: At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of P-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines and design optimal protocols for work extraction. For two specific cycles, a quantum Otto and a generalised one, we show that non-classicality is a fundamental resource for performing thermodynamic tasks more efficiently.

SUBMITTER: de Oliveira Junior A

PROVIDER: S-EPMC9213435 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature

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Unravelling the non-classicality role in Gaussian heat engines.

de Oliveira Junior A A de Oliveira Marcos César MC

Scientific reports 20220621 1

At the heart of quantum thermodynamics lies a fundamental question about what is genuine "quantum" in quantum heat engines and how to seek this quantumness, so that thermodynamical tasks could be performed more efficiently compared with classical protocols. Here, using the concept of P-representability, we define a function called classicality, which quantifies the degree of non-classicality of bosonic modes. This function allows us to explore the role of non-classicality in quantum heat engines ...[more]

PMID: 35729309

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Project description:Despite the remarkable success of Carnot's heat engine cycle in founding the discipline of thermodynamics two centuries ago, false viewpoints of his use of the caloric theory in the cycle linger, limiting his legacy. An action revision of the Carnot cycle can correct this, showing that the heat flow powering external mechanical work is compensated internally with configurational changes in the thermodynamic or Gibbs potential of the working fluid, differing in each stage of the cycle quantified by Carnot as caloric. Action (@) is a property of state having the same physical dimensions as angular momentum (mrv = mr2ω). However, this property is scalar rather than vectorial, including a dimensionless phase angle (@ = mr2ωδφ). We have recently confirmed with atmospheric gases that their entropy is a logarithmic function of the relative vibrational, rotational, and translational action ratios with Planck's quantum of action ħ. The Carnot principle shows that the maximum rate of work (puissance motrice) possible from the reversible cycle is controlled by the difference in temperature of the hot source and the cold sink: the colder the better. This temperature difference between the source and the sink also controls the isothermal variations of the Gibbs potential of the working fluid, which Carnot identified as reversible temperature-dependent but unequal caloric exchanges. Importantly, the engine's inertia ensures that heat from work performed adiabatically in the expansion phase is all restored to the working fluid during the adiabatic recompression, less the net work performed. This allows both the energy and the thermodynamic potential to return to the same values at the beginning of each cycle, which is a point strongly emphasized by Carnot. Our action revision equates Carnot's calorique, or the non-sensible heat later described by Clausius as 'work-heat', exclusively to negative Gibbs energy (-G) or quantum field energy. This action field complements the sensible energy or vis-viva heat as molecular kinetic motion, and its recognition should have significance for designing more efficient heat engines or better understanding of the heat engine powering the Earth's climates.

Dataset Information

Unravelling the non-classicality role in Gaussian heat engines.

Publications

Unravelling the non-classicality role in Gaussian heat engines.

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