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Solid-state molecular oxygen activation using ball milling and a piezoelectric material for aerobic oxidation of thiols.

ABSTRACT: The agitation of BaTiO₃ via ball milling converts mechanical energy into electrical energy, leading to the reduction of molecular oxygen via a single electron transfer pathway analogous to the photocatalytic reaction. This mechanoredox strategy for the oxidative coupling of thiols could eliminate waste and develop a recyclable methodology to accomplish organic transformations in a greener fashion, exhibiting promising potential for large-scale chemical manufacturing.

SUBMITTER: Wang G

PROVIDER: S-EPMC9214485 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature

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Solid-state molecular oxygen activation using ball milling and a piezoelectric material for aerobic oxidation of thiols.

Wang Gefei G Jia Jiajia J He Yu Y Wei Diandian D Song Mingyu M Zhang Lei L Li Ganzhong G Li Heng H Yuan Bingxin B

RSC advances 20220622 29

The agitation of BaTiO3 via ball milling converts mechanical energy into electrical energy, leading to the reduction of molecular oxygen via a single electron transfer pathway analogous to the photocatalytic reaction. This mechanoredox strategy for the oxidative coupling of thiols could eliminate waste and develop a recyclable methodology to accomplish organic transformations in a greener fashion, exhibiting promising potential for large-scale chemical manufacturing. ...[more]

PMID: 35799932

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