Water Oxidation by Pentapyridyl Base Metal Complexes? A Case Study.

ABSTRACT: The design of molecular water oxidation catalysts (WOCs) requires a rational approach that considers the intermediate steps of the catalytic cycle, including water binding, deprotonation, storage of oxidizing equivalents, O-O bond formation, and O₂ release. We investigated several of these properties for a series of base metal complexes (M = Mn, Fe, Co, Ni) bearing two variants of a pentapyridyl ligand framework, of which some were reported previously to be active WOCs. We found that only [Fe(Py5OMe)Cl]⁺ (Py5OMe = pyridine-2,6-diylbis[di-(pyridin-2-yl)methoxymethane]) showed an appreciable catalytic activity with a turnover number (TON) = 130 in light-driven experiments using the [Ru(bpy)₃]²⁺/S₂O₈^2-

SUBMITTER: Boniolo M 

PROVIDER: S-EPMC9214691 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature