Plastic Monolithic Mixed-Conducting Interlayer for Dendrite-Free Solid-State Batteries.

ABSTRACT: Solid-state electrolytes (SSEs) hold a critical role in enabling high-energy-density and safe rechargeable batteries with Li metal anode. Unfortunately, nonuniform lithium deposition and dendrite penetration due to poor interfacial solid-solid contact are hindering their practical applications. Here, solid-state lithium naphthalenide (Li-Naph(s)) is introduced as a plastic monolithic mixed-conducting interlayer (PMMCI) between the garnet electrolyte and the Li anode via a facile cold process. The thin PMMCI shows a well-ordered layered crystalline structure with excellent mixed-conducting capability for both Li⁺ (4.38 × 10^-3  S cm^-1 ) and delocalized electrons (1.01 × 10^-3  S cm^-1 ). In contrast to previous composite interlayers, this

SUBMITTER: Xiong BQ 

PROVIDER: S-EPMC9218657 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature