Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas.

ABSTRACT: A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe.

SUBMITTER: Pan J 

PROVIDER: S-EPMC9229220 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature