Back Interface Passivation for Efficient Low-Bandgap Perovskite Solar Cells and Photodetectors.

ABSTRACT: Low-bandgap (E_g~1.25 eV) mixed tin-lead (Sn-Pb) perovskites are promising candidates for efficient solar cells and self-powered photodetectors; however, they suffer from huge amounts of defects due to the unintentional p-type self-doping. In this work, the synergistic effects of maltol and phenyl-C61-butyric acid methyl ester (PCBM) were achieved to improve the performance of low-bandgap perovskite solar cells (PSCs) and unbiased perovskite photodetectors (PPDs) by passivating the defects and tuning charge transfer dynamics. Maltol eliminated the Sn-related traps in perovskite films through a strong metal chelating effect, whereas PCBM elevated the built-in electric potential and thus improved voltage through the spike energy alignment. Combining both advantages of maltol and PC

SUBMITTER: Lu J 

PROVIDER: S-EPMC9231224 | biostudies-literature | 2022 Jun

REPOSITORIES: biostudies-literature