When Identification of the Reduction Sites in Mixed Molybdenum/Tungsten Keggin-Type Polyoxometalate Hybrids Turns Out Tricky.

ABSTRACT: The mixed molybdenum/tungsten Keggin-type polyoxometalate (POM) hybrid (TBA)₄[PW₉Mo₂O₃₉{Sn(C₆H₄I)}] (TBA = tert-butylammonium) has been prepared by the reaction between [α-PW₉Mo₂O₃₉]^7- and [Cl₃Sn(C₆H₄I)] in dried acetonitrile, in the presence of tetra-n-butylammonium bromide. A further coupling reaction affords the ferrocenyl derivative (TBA)₄[PW₉Mo₂O₃₉{Sn(C₆H₄)C≡C(C₆H₄)Fc}]. The POM hybrids have been thoroughly characterized by NMR and IR spectroscopies. Electrochemical analysis confirms their ease of reduction compared to the all-W analogue, albei

SUBMITTER: Laurans M 

PROVIDER: S-EPMC9234957 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature